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Passive Adiabatic Effect: Cold sky reflection on IR imagery.

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I am currently in training to become an analyst using thermal imagery. In the studies I have been introduced to cold sky reflection on thermal imagery, however the instructor explained it as a surface 'reflecting the cold from the sky' which, as far as I'm aware, doesnt fit with the second law of thermodynamics. Can someone provide me with an explanation of what causes this effect?

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