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Why electrolytes decompose so easily?

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Why supercaps could withstand only 2-5 V before electrolyte starts to decompose?
And solid electrolyte such as proton conductor could withstand no more than a few volts?
Superionic conductors such as RbAgI could withstand easily according to some data only 0.5 V (should be verified).In the same time electronic conductors could withstand millions of volts without any consequences.How ability to conduct ions are connected to proneness to decompose easily even under low voltage?

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