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Pressure and energy correlation?

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What's the correlation between energy and pressure?
Is it E=P*V ? where E - energy, P - pressure, V - volume
And for example lets say X represents Earth's atmosphere pressure and Y - pressure of the gas contained in a can. Is the potential energy that could be released in Earth's atmosphere (lets say blow up a can of compressed air) E=(Y-X)*V ? Is it correct?

Btw.
Anyone know what are the common pressures of gases in a deodorant can? I've searched on google but found nothing.

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