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Uniform Field & Poisson equation Mismatch?

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Hi,

I'm getting some confusing results and cant figure out what is wrong
Suppose we have a uniform field

[itex]E=[0,0,E_z][/itex] in a dielectric media.

By [itex]E=-\nabla\psi [/itex] we can deduce that [itex]\psi(x,y,z)=-z E_z[/itex]

But, taking the Laplacian
[itex]\nabla^2\psi=\frac{\partial^2 (-zE_z)}{\partial z^2}=0[/itex]
does not match the results of the Poisson equation
[itex]\nabla^2\psi=-\frac{\rho}{\epsilon_m \epsilon_o}[/itex]

what am I missing?

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