In a problem in Callen's book I was asked to say what was the latent heat of fusion at the triple point for ammonia. I answered "without performing any algebra, 0J". Because I remember a video I saw on youtube about the triple point (http://www.youtube.com/watch?v=BLRqpJN9zeA) and now I read on wikipedia
which seem to confirm that indeed, the system can undergo a phase transition without any external heat transfer.
So would the triple point be equivalent to a critical point in some way? In the sense that if I understood well, in a critical point the system can change its phase without any external heat, just like in the triple point?
Quote:
Quote by Wiki The Great
At that point, it is possible to change all of the substance to ice, water, or vapor by making arbitrarily small changes in pressure and temperature.
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So would the triple point be equivalent to a critical point in some way? In the sense that if I understood well, in a critical point the system can change its phase without any external heat, just like in the triple point?